Question 1

Where is Tokyo Metropolitan Government Building?

Accepted Answer

Tokyo Metropolitan Government Building is in Shinjuku, Tokyo, Japan. You can see its exact position from the map coordinates and the Street View link.

Question 2

Which scene of The Devil is a Part-Timer! does Tokyo Metropolitan Government Building appear in?

Accepted Answer

Tokyo Metropolitan Government Building appears in EP12 of The Devil is a Part-Timer!.

Question 3

Can I visit Tokyo Metropolitan Government Building?

Accepted Answer

Yes. Tokyo Metropolitan Government Building is a real place you can visit. Check what it looks like on Street View before you go.

Question 4

Where was The Devil is a Part-Timer! filmed?

Accepted Answer

Anime and manga are not filmed the way live action is. Their backgrounds are painted from photographs of real locations, and Tokyo Metropolitan Government Building is one of those real places (EP12).